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论文摘要

壳聚糖改性材料用于海水提铀研究

Study on uranium extraction from seawater with chitosan modified materials

作者:董浩(西南科技大学国防科技学院);文君(中国工程物理研究院核物理与化学研究所);卢喜瑞(西南科技大学国防科技学院)

Author:DONG Hao(College of National Defense Science and Technology, Southwest University of Science and Technology);WEN Jun(Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics);LU Xi-Rui(College of National Defense science and Technology, Southwest University of Science and Technology)

收稿日期:2019-10-07          年卷(期)页码:2020,57(1):163-168

期刊名称:四川大学学报: 自然科学版

Journal Name:Journal of Sichuan University (Natural Science Edition)

关键字:壳聚糖;吸附;交联;铀

Key words:Chitosan; Adsorption; Crosslinking; Uranium

基金项目:国家自然科学基金

中文摘要

通过在壳聚糖上交联偕胺肟基(AO)和1-二甲胺基烯丙基膦酸(DMAAPA),制备出一种可用于海水提铀的新型壳聚糖改性材料(CTS-AM-AO-DA),使用FT-IR光谱和扫描电镜表征材料表面的官能团和形貌.通过吸附实验研究了材料在模拟海水中的吸附动力学过程和溶液pH、盐分以及竞争离子对材料吸附性能的影响.CTS-AM-AO-DA在模拟海水中的平衡吸附容量达到223.0 mg/g,吸附过程符合准二级动力学方程.在高pH(8.0)、高盐分(0.5 mol/L NaCl)、存在竞争离子(钙、镁、钒)的条件下,CTS-AM-AO-DA均表现出优异的铀吸附性能,该材料在海水提铀领域具有潜在的应用价值.

英文摘要

A novel chitosan modified material, CTS-AM-AO-DA was synthesized through the crosslinking of chitosan with amidoxime group and (1-(dimethylamino)allyl) phosphonic acid (DMAAPA) as the uranium adsorbent from seawater. The chemical structures and appearance of the polymers were characterized by the FT-IR spectrum and the SEM. The adsorption kinetics in simulated seawater and the effects of solution pH, salinity, and competing ions on the adsorption properties of materials were studied by using adsorption experiments. The equilibrium adsorption capacity of CTS-AM-AO-DA is 223 mg/g and the adsorption dynamic data are applicable to the quasi-second-order model. Weak alkalinity (8.0), high salinity (0.5 mol/L) or the presence of competitive ions (Ca2+, Mg2+, V5+) can not affect the adsorption properties of this material (CTS-AM-AO-DA) that provides the potential applications in real seawater environment.

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