Micro- and nano-scale metal-organic complexs not only have size effect, but have an adjustable assembly unit, which shows a lot of good performance. in this paper, we synthesized nanoscale mertal-porphyrin complexs by a simple and green method. by choosing the different metal ions, the different nanostructures (0D, 1D, 2D) of metal-porphyrin polymer was abtained by controlled assemble unit. its structures were characterizatized by scanning electron microscopy (SEM), infrared spectroscopy (IR), x-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), and were detailed examinated of the impact and dynamica growth of the metal-porphyrin polymer.
