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论文摘要

Sb含量对Ni46Mn41In13-xSbx结构、相变和磁性的影响

Influences of Sb content on the structure, phase transition and magnetism of Ni46Mn41In13-xSbx alloys

作者:刘红艳(菏泽学院物理与电子工程学院);李宏(淮北师范大学物理与电子信息学院)

Author:LIU Hong-Yan(College of Physics and Electronic Engineering, Heze University);LI Hong(School of Physics and Electronic Information, Huaibei Normal University)

收稿日期:2017-10-19          年卷(期)页码:2018,55(2):371-374

期刊名称:四川大学学报: 自然科学版

Journal Name:Journal of Sichuan University (Natural Science Edition)

关键字:Ni-Mn-In; 结构转变; 马氏体相变; 磁性

Key words:Ni-Mn-In; structural transition; martensitic transformation; magnetism

基金项目:省自然科学基金

中文摘要

系统研究了铁磁形状记忆合金Ni46Mn41In13-xSbx (x=0, 2, 4, 6, 8, 10, 12, 13)的结构、相变和磁性能。研究表明:系列合金仍然为L21立方结构,原子排列有序度有所提高。居里温度和马氏体逆相变温度在x6时均随x的增大而逐渐升高。磁化强度-温度曲线显示,Sb 对In的替代引起主族元素p轨道和过渡族金属d轨道之间p-d轨道杂化作用改变,导致Ni46Mn41In13-xSbx奥氏体和马氏体磁化强度变化趋势随Sb含量的增加出现反转。

英文摘要

The structure, phase transition and magnetism of Ni46Mn41In13-xSbx (x=0, 2, 4, 6, 8, 10, 12, 13) alloys have been systematically studied in this paper. The results demonstrate that the arc-melting samples display pure L21-type and atoms are arranged more orderly. Curie temperature and martensitic inverse transformation temperature reduce at x6 gradually with increasing x. The magnetization-temperature curves indicate that substitution of In by Sb has a significant influence on the p-d hybridization interaction between p orbitals of main group element and d orbitals of transition metals, leading to a reverse trend of the magnetization of austenite and martensite with the increasing Sb content.

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