Objective To analyze the relationship between inorganic ingredien(ts Ca, P and F)concentration of plaque residues in the primary teeth and caries status,sugar exposure frequency. Methods Subjects were 93 of 3- 5 years old children living in Beijing area. According to their caries status, they were classified into two groups: Severe early childhood cari(es S- ECC)group and caries fre(e CF)group. Plaque samples were collected from subjects respectively. Ca, P and F concentration of plaque residues was measured by atomic absorption spectroscopy, spectrophotometer and fluoride electrode respectively. The information of daily sugar exposure frequency of children was obtained from a standardized questionnaire filled by their parents. The relationship between inorganic ingredients ( Ca, P and F) concentration of plaque residues and daily sugar exposure frequency was analyzed and the relationship between inorganic ingredien(ts Ca, P and F)concentration of plaque residues and caries status in the SECC group was also analyzed. Results The mean values for Ca, P and F concentration of plaque residues were lower in the S- ECC group, but the difference was not statistically significan(t P>0.05). The daily sugar exposure frequency in the S- ECC group was higher than that in the CF group. There were no relationships between Ca, P and F concentration of plaque residues and caries stat(us dmft, dmfs), sugar exposure frequency in the primary dentition. Conclusion Plaque residues from CF subjects did not contain a greater pool of calcium, inorganic phosphorus, and fluoride ions than that from S- ECC subjects.