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论文摘要

钛表面阳极氧化膜的腐蚀行为研究

Study of corrosion behavior of titanium with anodized oxidation film

作者:于卫强 邱憬 张富强

Author:YU Wei-qiang1,2, QIU Jing1,2, ZHANG Fu-qiang1

收稿日期:2011-04-25          年卷(期)页码:2011,29(02):203-203-205

期刊名称:华西口腔医学杂志

Journal Name:West China Journal of Stomatology

关键字:钛,阳极氧化,煅烧,腐蚀性能,

Key words:titanium,anodized oxidation,annealing,corrosion behavior,

基金项目:

上海市科学技术委员会基金资助项目(08DZ2271100);上海市重点学科建设基金资助项目(S30206);上海市重点学科(特色学科)建设基金资助项目(T0202);上海市纳米专项基金资助项目(1052-nm04300)

中文摘要

目的探讨钛阳极氧化前后腐蚀性能的变化。方法钛表面阳极氧化法制备TiO2纳米管,扫描电镜观察氧化膜的微结构,X线衍射分析氧化膜煅烧前后晶型的变化,极化曲线分析钛阳极氧化前后对腐蚀性能的影响。结果阳极氧化后,钛表面呈现管径80 nm,管长400 nm的纳米管状结构;X线衍射分析表明阳极氧化膜煅烧后变为锐钛矿晶型;电化学实验表明:光滑钛的破钝电位低于煅烧前后的阳极氧化膜(P

英文摘要

Objective To investigate the variation of the corrosion resistance of anodized oxidation film on titanium by electrochemical methods. Methods TiO2 nanotube layer was formed on Ti surface by anodization. The morphology was observed with scanning electron microscope(SEM) and the crystal phase was analyzed using X-ray diffraction(XRD) before and after annealing. Polarization curves were examined by electrochemical methods. Results Titanium oxide nanotubes with 80 nm diameter and 400 nm length was seen on Ti after anodization. The annealing nanotubes was anatase crystalline phase by X-ray diffraction analysis. The self-corrosion potential and break-down potential of smooth Ti were significantly lower than TiO2 nanotubes by anodization(P

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