硝酸-冰乙酸腐蚀对CdTe太阳电池性能的影响
Effect of Nitric acetic Acid Etching on the Properties of CdTe Solar Cells
作者:李卫(四川大学 材料科学与工程学院,四川 成都610064);冯良桓(四川大学 材料科学与工程学院,四川 成都610064);蔡亚平(四川大学 材料科学与工程学院,四川 成都610064)
Author:(School of Materials Sci. and Eng.,Sichuan Univ.,Chengdu 610065,China);(School of Materials Sci. and Eng.,Sichuan Univ.,Chengdu 610065,China);(School of Materials Sci. and Eng.,Sichuan Univ.,Chengdu 610065,China)
收稿日期:2006-11-17 年卷(期)页码:2007,39(4):109-112
期刊名称:工程科学与技术
Journal Name:Advanced Engineering Sciences
关键字:腐蚀;背接触;CdTe太阳电池
Key words:etch;back contact;CdTe solar cells
基金项目:国家高技术研究与发展计划(2003AA513010);四川省科技攻关项目(05GG021-003-3);辐射物理及技术教育部重点实验室(四川大学)
中文摘要
在CdTe与金属背电极间形成稳定的低电阻接触,有助于提高CdTe太阳电池性能。采用硝酸-冰乙酸腐蚀CdTe薄膜并用真空蒸发法沉积铜背接触层,制备CdTe太阳电池。结果表明,化学腐蚀后在膜面生成了富碲层,硝酸-冰乙酸腐蚀为各向同性刻蚀。对背接触层进行优化退火处理,获得转化效率11.75%的CdTe太阳电池。
英文摘要
Forming a low resistance contact to CdTe thin films is a key issue for successful improvement of the performance of CdTe solar cells. The CdTe thin films were etched with nitric-acetic (NA) acid and a Cu back contact layer was deposited onto the etched CdTe surface, then the CdTe solar cells were fabricated. The results indicated that the nitric acetic acid pretreatment forms a highly conductive Te layer on the back surface of the CdTe thin films and it is an isotropic etching. An efficiency of 11.75% for CdTe solar cells was obtained when the back contact layer was annealed under optimum conditions.
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