A new type of SM carbon coated optical fiber was tested using the concrete models of optical fiber crack sensing to get its mechanic optic constitutive relation and performance characteristics of concrete structural crack monitoring. The results indicated that the carbon coated optical fiber is able to monitor the development of the crack with high sensitivityof 0.02 mm and its dynamic range of 1~4.5 mm is larger significantly than the common SM optical fiber. Thereby it could offset the disadvantages of common SM optic-fibers for crack monitoring and be used in severe conditions.