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论文摘要

聚丙烯/液晶/马来酸酐接枝聚丙烯复合材料的结构性能

Structure Properties of PP/LCP/PP-g-MAH Composites Prepared by Melt Blending

作者:李又兵(重庆理工大学 材料科学与工程学院;重庆市模具技术重点实验室);孙珍珍(重庆理工大学 材料科学与工程学院);王恒兵(重庆理工大学 材料科学与工程学院);潘燕(重庆理工大学 材料科学与工程学院);史文(重庆理工大学 材料科学与工程学院)

Author:Li Youbing(College of Materials Sci. and Eng., Chongqing Univ. of Technol.;Chongqing Mold Technique Key Lab.);Sun Zhenzhen(College of Materials Sci. and Eng., Chongqing Univ. of Technol.);Wang Hengbing(College of Materials Sci. and Eng., Chongqing Univ. of Technol.);Pan Yan(College of Materials Sci. and Eng., Chongqing Univ. of Technol.);Shi Wen(College of Materials Sci. and Eng., Chongqing Univ. of Technol.)

收稿日期:2012-03-17          年卷(期)页码:2012,44(5):190-194

期刊名称:工程科学与技术

Journal Name:Advanced Engineering Sciences

关键字:液晶;聚丙烯;熔融共混;取向;增韧

Key words:iquid crystalline polymer;polypropylene;melt blending;orientation;toughening

基金项目:重庆市科技攻关计划资助项目(CSTC;2011AC4121);重庆市自然基金资助项目(CSTC;2010BB4305);重庆市教委资助项目(KJ110809);重庆理工大学博士点基金预研基金资助项目(099-55-01-201014)

中文摘要

选用液晶聚合物(LCP)对聚丙烯(PP)进行熔融共混,采用马来酸酐接枝聚丙烯(PP-g-MAH)对PP/LCP复合材料进行改性,采用热分析(DSC)和电子扫描电镜(SEM)对复合材料结构与性能进行研究。研究发现:添加少量液晶对PP具有一定的增强和增韧作用,与纯PP相比,PP/LCP(100/10)拉伸强度和冲击强度分别提高了5.4%和21.3%;在PP-g-MAH接枝改性后,PP/LCP/PP-g-MAH(100/10/3)比PP/LCP(100/10)拉伸强度提高了18.5%,冲击强度提高了33.2%。增加LCP含量,提高了PP/LCP共混物中PP组分熔融温度,但是结晶度降低;加入少量的PP-g-MAH,提高了PP/LCP/PP-g-MAH共混物耐热温度和PP组分结晶度。SEM照片显示,加入液晶组分,有利于PP/LCP共混物形成取向结构;加入PP-g-MAH,有利于LCP形成取向微纤,改善制品的综合性能。

英文摘要

A commercial liquid crystalline polymer(LCP) was used to blend with polypropylene(PP), and a PP-g-MAH was used to improve the compatibilization of PP and LCP. The structure-properties of PP/LCP and PP/LCP/PP-g-MAH composites were studied with DSC and SEM. The results showed that the addition of a little LCP is beneficial for strengthening and reinforcing PP/LCP blends. Compared with pure PP, the impact strength and tensile strength of PP/LCP(100/10) is increased by 21.3% and 5.4%, respectively. With the addition of LCP, the melt temperature of PP component is increased while its crystallinity decreased. Compared with PP/LCP(100/10) blend, the addition of PP-g-MAH, increases the tensile strength and impact strength of PP/LCP/PP-g-MAH(100/10/3) blend. SEM photos showed that, with the addition of LCP component the preferred orientation structure is formed for PP/LCP blends, and the preferred orientation of LCP microfiber is formed with the addition of PP-g-MAH, which are beneficial for enhancing article’s over-all properties.

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