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论文摘要

AgGa0.6In0.4Se2晶体的制备与表征

Preparation and Characterization of AgGa0.6In0.4Se2 Crystals

作者:万书权(四川大学 材料科学与工程学院);朱世富(四川大学 材料科学与工程学院);赵北君(四川大学 材料科学与工程学院);陈宝军(四川大学 材料科学与工程学院);何知宇(四川大学 材料科学与工程学院);许建华(四川大学 材料科学与工程学院);刘勇(四川大学 材料科学与工程学院)

Author:Wan Shuquan(School of Materials Sci. and Eng., Sichuan Univ.);Zhu Shifu(School of Materials Sci. and Eng., Sichuan Univ.);Zhao Beijun(School of Materials Sci. and Eng., Sichuan Univ.);Chen Baojun(School of Materials Sci. and Eng., Sichuan Univ.);He Zhiyu(School of Materials Sci. and Eng., Sichuan Univ.);Xu Jianhua(School of Materials Sci. and Eng., Sichuan Univ.);Liu Yong(School of Materials Sci. and Eng., Sichuan Univ.)

收稿日期:2010-10-29          年卷(期)页码:2011,43(3):194-197

期刊名称:工程科学与技术

Journal Name:Advanced Engineering Sciences

关键字:硒铟镓银;单晶;性能表征;光学材料

Key words:AgGa1-xInxSe2;single crystals;characterization;optical materials

基金项目:教育部博士点基金资助项目(20040610024)

中文摘要

以高纯单质为原料,按AgGa1-xInxSe2(x=0.4)化学计量配比配料(富1%Se),在双层石英安瓿中,用机械和温度振荡相结合的方法,合成出高纯单相多晶料。差热分析表明,其熔点和凝固点分别为804.3 ℃和775.6 ℃。采用带有籽晶袋、内壁镀碳的双层石英安瓿,用改进的垂直布里奇曼法生长出尺寸为Φ20 mm×60 mm、结构完整的AgGa0.6In0.4Se2单晶体。经X射线衍射仪和红外分光光度计等分析表明,晶体为黄铜矿结构,晶格常数为a=0.602 32 nm,c=1.118 33 nm,其显露面和易解理面为(112)面;厚度约为2 mm的晶片在波长0.836~19.65 μm范围内透过率接近或超过60%,禁带宽度约为1.48 eV。结果表明,改进方法生长的AgGa1-xInxSe2晶体的结构完整,光学质量高,可用于中远红外非线性光学器件制备。

英文摘要

AgGa0.6In0.4Se2 polycrystalline materials were synthesized by mechanical and temperature oscillation method in a two-layer quartz ampoule using high-purity elements according to the stoichiometry with an excess of 1% Se. The melting and freezing points of the materials were determined to be 804.3 ℃ and 775.6 ℃, respectively, through thermal analysis. A crack-free AgGa0.6In0.4Se2 crystal of Φ20 mm×60 mm was grown by modified vertical Bridgman method in a two-layer carbon coated quartz ampoule with specially designed seed pocket. The crystal was with chalcopyrite structure. The lattice constants of aand cwere 0.602 32 nm and 1.118 33 nm, respectively. The reflection faces and cleavage face were (112) faces. A wafer with 2 mm thickness was cut from the as-grown crystal. Its transmittance was up to or more than 60% in a range of 0.836~19.65 μm. Its calculated band gap was about 1.48 eV. The results proved that the grown crystal was of integral structure and high quality, and it can be used for fabrication of mid-far infrared nonlinear optical devices.

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