期刊导航

论文摘要

苯并噁嗪/环氧树脂/咪唑三元体系的固化动力学及固化工艺研究

Curing Kinetics and Process of a Ternary Blend of Benzoxazine/Epoxy Resin/Imidazole

作者:张华川(高分子材料工程国家重点实验室,四川大学 高分子科学与工程学院);冉起超(高分子材料工程国家重点实验室,四川大学 高分子科学与工程学院);顾宜(高分子材料工程国家重点实验室,四川大学 高分子科学与工程学院)

Author:Zhang Huachuan(State Key Lab. of Polymer Materials Eng., School of Polymer Sci. and Eng., Sichuan Univ.);Ran Qichao(State Key Lab. of Polymer Materials Eng., School of Polymer Sci. and Eng., Sichuan Univ.);Gu Yi(State Key Lab. of Polymer Materials Eng., School of Polymer Sci. and Eng., Sichuan Univ.)

收稿日期:2010-11-24          年卷(期)页码:2011,43(5):228-233

期刊名称:工程科学与技术

Journal Name:Advanced Engineering Sciences

关键字:苯并噁嗪;环氧;咪唑;固化动力学;固化工艺

Key words:benzoxazine;epoxy; imidazole; cure kinetics;cure process

基金项目:国家自然科学基金资助项目(50873062)

中文摘要

使用二苯甲烷二胺型苯并噁嗪(B)、环氧树脂F-51、咪唑制备了一种三元共混树脂体系(BFM),采用非等温DSC测试方法,基于Kissinger,Ozawa,Friedman,Flynn-Wall-Ozawa等理论模型对BFM的固化动力学进行了分析研究。结果表明,体系中主要存在两种反应,计算得到两者的表观活化能分别为85.05、37.3 kJ/mol,反应级数分别为0.8、1.6。以此得出了相应的动力学方程。此外,基于得到的动力学参数,结合体系固化反应特点,提出了一种预测固化时间的方法,从而确定了固化工艺。

英文摘要

A ternary blend resin(BFM) was prepared by diaminodiphenylmethane-based-benzoxazine(B), epoxy F-51 and imidazole. The curing kinetics of BFM resin was investigated by non-isothermal differential scanning calorimetry (DSC) according to Kissinger,Ozawa, Friedman and Flynn-Wall-Ozawa methods. There were two strong exothermal peaks in the DSC thermograms of BFM resin, which were corresponding to two kinds of curing reactions with the apparent activation energy of 85.05 kJ/mol and 137.3 kJ/mol, respectively. The reaction orders of the two kinds of reaction were 0.8 and 1.6, respectively. Furthermore, the curing process of BFM resin was established from a method proposed to determine the curing time,based on its curing reaction and kinetic parameters.

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