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论文摘要

碱金属元素掺杂比例对聚磷酸钙降解和矿化性能的影响

Effects of Doping Alkaline Metal Proportion on Degradation and Mineral Precipitation of Calcium Polyphosphate

作者:宋巍(四川大学高分子科学与工程学院);徐源廷(四川大学 高分子科学与工程学院,四川 成都610065);贾二鹏(四川大学高分子科学与工程学院);孙慧敏(四川大学高分子科学与工程学院);何冠松(四川大学高分子科学与工程学院);田野菲(四川大学高分子科学与工程学院);余喜讯(四川大学高分子科学与工程学院)

Author:Song Wei();XU Yuan-ting();Jia Erpeng();Sun Huimin(College of polymer science and engineering);He Guansong();();Yu Xixun(College of polymer science and engineering)

收稿日期:2008-11-30          年卷(期)页码:2009,41(6):124-129

期刊名称:工程科学与技术

Journal Name:Advanced Engineering Sciences

关键字:聚磷酸钙;碱金属;掺杂;降解;矿化沉积

Key words:calcium polyphosphates(CPP);alkali metals;doping;degradation;mineral precipitation

基金项目:国家自然科学基金资助项目(30870616);江苏省自然科学基金资助项目(BK2008152);四川省科技厅应用基础研究项目(07JY029-075);四川大学创新型实验计划重点项目

中文摘要

用不同比例的碱金属钾(K)和钠(Na)对聚磷酸钙(CPP)进行掺杂改性以期研究其降解与矿化性能。掺杂CPP样品在模拟体液(SBF)中分别浸泡1、2、3、7、14、21、28和35 d,研究其降解和矿化性能。通过测量降解样品的失重率,SBF中Ca2+和PO43-的浓度和pH值的变化来表征降解速率。掺杂CPP样品通过X射线衍射法(XRD)、傅里叶红外变换光谱法(FTIR)和扫描电镜(SEM)进行表征。结果显示掺杂摩尔比高于5%的CPP降解速率明显提高。K+ 和 Na+掺杂比越高越能有效提高CPP的降解和矿化能力。

英文摘要

Calcium polyphosphates(CPP)were modified by doping alkali metals ions(K+ and Na+ ) with different proportions to study its degradability and mineralization ability. Doped CPP samples were immersed in simulated body fluids(SBF) during 1,2,3, 7,14,21,28 and 35 days to study the degradability and mineralization ability. The weight loss of degraded samples, Ca2+and PO43-concentrations change, and pH value in SBF were measured to characterize the degradability. Doped CPP samples were characterized by XRD, FTIR and SEM. The results showed that doping proportion with molar ratio higher than 5% largely accelerated degradation rate. Higher doping proportion of K+ and Na+ resulted in positive effect on the degradability and mineralization ability of CPP.

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