期刊导航

论文摘要

以镧离子掺杂硅胶为载体的 联吡啶钌对氧敏感性的研究

The Oxygen Sensitiveness of Tris(2,2'-bipyridine)ruthenium(Ⅱ) Based Lanthanum codoped Silica

作者:熊小莉(西南科技大学 材料学院,四川 绵阳 621000);肖丹(四川大学 化学工程学院 ,四川 成都 610065)

Author:(School of Materials, Southwest Univ. of Sci. and Technol., Sichuan Mianyang 621002, China);(School of Chem.Eng., Sichuan Univ., Chengdu 610065, China)

收稿日期:2005-09-30          年卷(期)页码:2006,38(1):72-75

期刊名称:工程科学与技术

Journal Name:Advanced Engineering Sciences

关键字:镧离子掺杂;硅胶;联吡啶钌;氧传感器

Key words:La-codoped silica gel; support system; Ru(bpy)32+; oxygen sensor

基金项目:西南科技大学青年预研基金资助项目(ZK043002)

中文摘要

为了改进以硅胶为载体的联吡啶钌对氧的响应灵敏度,采用了掺杂镧离子的硅胶做载体来固定敏感物质[Ru(bpy)3]Cl2,发现掺杂镧后样品对氧的响应倍数(I0/I)从4.6倍增大到14.4倍,响应曲线符合Stern-Volmer方程;重现性和稳定性良好;响应时间约10 s。该实验结果为发展氧传感器敏感物质的固定方法提供了一条新途径

英文摘要

n order to improve the sensitivity of the oxygen sensor based on tris(2,2′-bipyridine) ruthenium (Ⅱ) and [Ru(bpy)]Cl2 adsorbed onto silica particles, the La-codoped silica gel was used as the support system. Compared with reference (I0/I=4.6),The new oxygen sensor shows a high sensitivity to oxygen with a ratio of I0/I=14.4.The response accords with Stern-Volmer equation and the codoped sample has good repeatability and photostability, with response time approximately 10 s. This is a new approach to immobilize oxygen sensitive material for oxygen sensor.

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