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论文摘要

使用芳香醛对羊毛织物的染色方法研究

Study on the Dyeing Method of Wool Fabric with Aromatic Aldehydes

作者:董永春(天津工业大学 纺织学院 纺织化学与生态学研究中心,天津300160);韩振邦(天津工业大学 纺织学院 纺织化学与生态学研究中心,天津300160);高硕雁(天津工业大学 纺织学院 纺织化学与生态学研究中心,天津300160)

Author:(Division of Textile Chemistry and Ecology, School of Textiles, Tianjin Polytechnic Univ., Tianjin 300160, China);(Division of Textile Chemistry and Ecology, School of Textiles, Tianjin Polytechnic Univ., Tianjin 300160, China);(Division of Textile Chemistry and Ecology, School of Textiles, Tianjin Polytechnic Univ., Tianjin 300160, China)

收稿日期:2007-01-20          年卷(期)页码:2008,40(4):89-94

期刊名称:工程科学与技术

Journal Name:Advanced Engineering Sciences

关键字:芳香醛;色胺酸;羊毛织物;染色;氧化

Key words:aromatic aldehyde; tryptophan; wool fabric; dyeing; oxidation

基金项目:天津市“十一五”综合投资学科建设项目资助课题

中文摘要

在60 ℃和强酸性条件下分别使用对二甲氨基苯甲醛(DMAB)和对二乙氨基苯甲醛(DEAB)对羊毛机织物进行染色120 min,然后以H2O2进行氧化处理60 min。研究了DMAB、H2O2和HCl浓度等对染色羊毛织物表面深度和颜色特征的影响,并考察了其染色牢度和断裂强度。结果表明,染色浴中DMAB和HCl浓度的增加均能够明显提高羊毛织物的表面深度(K/S)和鲜艳度,并且在DMAB浓度或HCl浓度与最大吸收波长处的K/S值之间存在着线性关系。在氧化浴中H2O2和HCl浓度的升高有利于羊毛织物的表面深度和鲜

英文摘要

Wool woven fabric was dyed for 120 min with N, N-dimethyl-p-aminobenzaldehyde (DMAB) or N, N-diethyl-p-aminobenzaldehyde (DEAB) at 60 ℃ and acidic condition, and then oxidized with H2O2 for 60 min, respectively. Some factors affecting process such as the concentration of DMAB, H2O2 and HCl were investigated with respect to color strength and characteristics. Additionally, dyeing fastness and breaking strength of dyed wool fabrics were also evaluated. The results indicated that increasing concentration of DMAB or HCl in dyeing bath caused a significant enhance in color strength (K/S) and chroma. There is the linear relationship between concentration of DMAB or HCl in dyeing bath and K/S value. The K/S value and chroma were improved by increasing concentration of H2O2 and HCl in oxidation bath, but decreased when H2O2 concentration was above 0.175%(wt). Moreover, wool woven fabrics dyed with two aromatic aldehydes have high soaping and rubbing fastness as well as breaking strength.

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