小叶香茶菜中二萜类化学成分的研究
Study of diterpenoids constituents from Isodon parvifolius
作者:杨黎彬;黄胜雄;李丽梅;赵勇;普建新;
Author:
收稿日期: 年卷(期)页码:2013,28(03):-234-237
期刊名称:华西药学杂志
Journal Name:WEST CHINA JOURNAL OF PHARMACEUTICAL SCIENCES
关键字:小叶香茶菜;化学成分;二萜;结构鉴定;层析色谱
Key words:
基金项目:
中文摘要
目的研究云南中甸产的小叶香茶菜地上部分的二萜化学成分。方法采用硅胶色谱,半制备、制备HPLC分离纯化二萜化学成分,运用1HNMR、13CNMR、ESI-MS等技术鉴定结构。结果从云南中甸的小叶香茶菜地上部分共分离得到了14个二萜化合物,分别鉴定为hebeirubescensin L(Ⅰ),adenolin E(Ⅱ),trichokaurin(Ⅲ),effusanin B(Ⅳ),rabdoternin C(Ⅴ),baiyecrystal A(Ⅵ),rabdoternin A(Ⅶ),rabescensin C(Ⅷ),sodoponin(Ⅸ),longikaurin E(Ⅹ),rabdolasional(Ⅺ),isodonal(Ⅻ),trichorabdal A(ⅩⅢ),trichorabdal H(ⅩⅣ)。结论化合物Ⅶ、Ⅷ、Ⅻ和ⅩⅣ为首次从小叶香茶菜中分离得到。
参考文献
[1]Li YZ,Chen YZ.Diterpenoids from Rabdosia parvifolia[J].Phytochemistry,1992,31:221-222.
[2]Guo YW,Cheng PY.Diterpenoid constituents of Isodon parvifo-lia:Structure elucidation of the new diterpenoid,parvifolin[J].Chin Chem Lett,1992,3:633-634.
[3]Guo YW,Cheng PY,Xu MJ,et al.The structure of parvifoliside[J].Acta Bot Sin,1991,33:722-726.
[4]Guo YW,Cheng PY,Xu GY.The structure of parvifoliside fromIsodon parvifolia leaves[J].Chin Chem Lett,1991,2:377-380.
[5]Li YZ,Chen YZ.Diterpenoids from Rabdosia parvifolia[J].Phy-tochemistry,1990,29:3033-3034.
[6]Li LM,Li GY,Huang SX,et al.7,20-Epoxy-ent-kauranoidsfrom Isodon parvifolius[J].J Nat Prod,2006,69:645-649.
[7]Huang SX,Zhou Y,Pu JX,et al.Cytotoxic ent-kauranoid deriv-atives from Isodon rubescens[J].Tetrahedron,2006,62:4941-4947.
[8]Zhang RP,Zhang HJ,Lin ZW,et al.Diterpenoids from Isodonadenoloma[J].Phytochemistry,1992,31:4237-4240.
[9]Fujita E,Fujita T,Shibuya M.Terpenoids-Ⅺ:The structure andabsolute configuration of trichokaurin and its chemical conversioninto(-)-kaurene and diterpene alkaloids[J].Tetrahedron,1969,25:2517-2530.
[10]Fujita T,Takeda Y,Shingu T,et al.Structures of effusanins,anti-bacterial diterpenoids from Rabdosia effuse[J].Chem Lett,1980,9:1635-1638.
[11]Yoshio T,Ko-Ichi T,Fujita T,et al.Yoshinori M.RabdoterninsD-G,ent-7β,20-epoxykaurenes from Rabdosia ternifolia[J].Phytochemistry,1994,35:1513-1516.
[12]Chen SN,Chen S,Lin YZ,et al.Four new diterpenoids from Isod-on leucophylla[J].Chin Chem Lett,1998,11:1021-1024.
[13]Sun HD,Chao JH,Lin ZW,et al.The structure of Rubescensin C:A new minor diterpnoid isolated from Rabdosia rubescens[J].Chem Pharm Bull,1982,30:341-347.
[14]Hao H,Zhang HJ,Sun HD,et al.Diterpenoids from Rabdosiasetschwanensis[J].Phytochemistry,1990,29:2591-2595.
[15]Sun HD,Lin ZW,Minami Y,et al.On the constituents of Rabdo-sia ternifolia(D.Don)Hara:The structure of a new diterpenoid,Isodonoic acid[J].Yakugaku Zasshi,1982,102:887-890.
[16]Takeda Y,Fujita T,Sun HD,et al.Revision of structures of Isod-onal,rabdolasional and related diterpenoids[J].Chem PharmBull,1990,38:1877-188.
[17]Osawa K,Yasuda H,Maruyama T,et al.Antibacterial trichorabdalditerpenoids from Rabdosia trichocarpa[J].Phytochemistry,1994,36:1287-1291.
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