期刊导航

论文摘要

阳极氧化制备的钛表面不同微观形貌膜层耐腐蚀性研究

Corrosion resistant properties of different anodized microtopographies on titanium surfaces

作者:霍芳军,谢利,童兴野,王月婷,郭维华,田卫东,

Author:Huo Fangjun, Xie Li, Tong Xingye, Wang Yueting, Guo Weihua, Tian Weidong,

收稿日期:2015-04-15          年卷(期)页码:2015,33(6):646-646-650

期刊名称:华西口腔医学杂志

Journal Name:West China Journal of Stomatology

关键字:纯钛,阳极氧化,表面形貌,耐腐蚀性,

Key words:pure titanium,anodic oxidation,surface morphology,corrosion resistant property,

基金项目:国际科技合作计划基金资助项目(2011DFA51970);四川省科技支撑计划基金资助项目(2013SZ0185);中国博士后科学基金面上资助项目(2013M531972)

中文摘要

目的 探讨阳极氧化制备的钛表面不同微观表面形貌在人工模拟体液中的耐腐蚀性。方法 通过阳极氧化法处理纯钛样品(PT),制备亚微米多孔(S)、微米多孔(M)、微米-亚微米复合多孔(MS)3种不同微观表面形貌氧化钛膜层的样品。采用扫描电子显微镜(SEM)观察样品表面形貌特征,X射线衍射仪分析表面晶型组成,表面粗糙度仪测试表面粗糙度,并对膜层横断面样品行SEM扫描观察膜层横断面结构和测量膜层厚度。采用电化学综合测试系统测试样品在人工模拟体液中的自腐蚀电位(Ecorr)、自腐蚀电流密度(Icorr)和极化电阻(Rp),获得Tafel曲线。结果 阳极氧化对钛样品表面改性获得了微米多孔、亚微米多孔、微米-亚微米多孔3种不同的微观表面形貌。S样品氧化膜中的阻挡层厚度最大。阳极氧化处理后的样品比未处理的纯钛样品的耐腐蚀性增加;阳极氧化处理样品中,耐腐蚀性能由强到弱依次为S样品、M样品、MS样品,S样品的Ecorr最大,Icorr最小,Rp最大,耐腐蚀性能最优。结论 阳极氧化处理可以提高纯钛在人工模拟体液中的耐腐蚀性,亚微米多孔表面钛样品的耐腐蚀性能最优。

英文摘要

Objective To investigate the corrosion resistant properties of titanium samples prepared by anodic oxidation with different surface morphologies. Methods Pure titanium substrates were treated by anodic oxidation to obtain porous titanium films in micron, submicron, and micron-submicron scales. The surface morphologies, coating cross-sectional morphologies, crystalline structures, and surface roughness of these samples were characterized. Electrochemical technique was used to measure the corrosion potential (Ecorr), current density of corrosion (Icorr), and polarization resistance (Rp) of these samples in a simulated body fluid. Results Pure titanium could be modified to exhibit different surface morphologies by the anodic oxidation technique. The Tafel curve results showed that the technique can improve the corrosion resistance of pure titanium. Furthermore, the corrosion resistance varied with different surface morphologies. The submicron porous surface sample demonstrated the best corrosion resistance, with maximal Ecorr and Rp and minimal Icorr. Conclusion Anodic oxidation technology can improve the corrosion resistance of pure titanium in a simulated body fluid. The submicron porous surface sample exhibited the best corrosion resistance because of its small surface area and thick barrier layer.

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