The microwave absorbing characteristics of the mixtures of carbonaceous reducer and zinc kiln slag were measured by the technique of microwave cavity perturbation and the relationships between P(P=ωε″E2V) and the microwave absorbing characteristic of the mixtures were studied. The results indicated that when the particle size of the mixtures is in the range of 147~175 μm, the optimal proportions are 18% (coconut’s carbon:zinc kiln slag),28% (coke:zinc kiln slag) and 16% (graphite:zinc kiln slag),respectively. Under those proportions, ε″ and P reach sharply to maximums and the characteristics of microwave absorbing of mixtures change.