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论文摘要

灾后重建用板房夹层泡沫聚苯乙烯的回收与改性研究

recycle and modification of foam polystyrene used in portable shelter after earthquake

作者:傅强(四川大学)

Author:Fu Qiang()

收稿日期:2010-04-14          年卷(期)页码:2010,42(5):155-159

期刊名称:工程科学与技术

Journal Name:Advanced Engineering Sciences

关键字:聚苯乙烯,塑料回收,增韧,老化

Key words:Polystyrene, recycle, toughen, ageing

基金项目:国家自然科学基金

中文摘要

在四川“5•12”抗震救灾期间,地震灾区共建设板房62.5万套,其中成都有19万多套。按照灾后恢复重建和城市建设规划,数十万套活动板房将逐步拆除或回收利用,而如何回收利用板房泡夹层泡沫聚苯乙烯是一个重要的研究课题。本文以苯乙烯-丁二烯-苯乙烯嵌段共聚物(SBS)作为增容剂,通过乙烯-辛烯共聚物(POE)和不同分子量的高密度聚乙烯(HDPE)来协同增韧回收废旧聚苯乙烯(rPS)。通过rPS/POE/HDPE/SBS四元体系制得的废旧PS复合材料的冲击强度为12.6 kJ/m2,拉伸强度为25.2 MPa,可以替代高抗冲聚苯乙烯(HIPS)使用,具有很好的经济效益和环境效益。而添加复配抗老化配方后,复合材料的抗紫外老化和抗热氧老化性能均得到提高,大大延长了复合材料的使用寿命。

英文摘要

There are many portable shelter which mainly contained foam Polystyrene(PS) need be recycled after earthquake. Recycled polystyrene (rPS) is not degradable which will cause serious environment pollution, so the large amount of disposable polystyrene plastic wastes produced after earthquake makes imperative the search for recycling them. In this work, rPS was toughened with ethylene-octylene copolymer thermoplastic elastomer (POE) and high-density polyethylene (HDPE), compatibilized by styrene-butadiene-styrene copolymer (SBS) in order to enhance the toughness of rPS. The prepared blend showed an impact strength of 12.6 kJ/m2 and a tensile strength of 25.2 MPa, which can be well used to substitute HIPS since this system is economical and environmental friendly. The properties of composite for UV ageing resistance and thermal and oxygenic ageing resistance were both improved after the addition of complex ageing resistance agent, which will prolong the using time of the composite parts.

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