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论文摘要

X80管线钢及其焊缝在库尔勒土壤环境中腐蚀行为

Corrosion Behavior of X80 Pipeline Steel and Its Weld Joint in Ku’erle Soil Environment

作者:吴明(辽宁石油化工大学 石油天然气工程学院);谢飞(辽宁石油化工大学 石油天然气工程学院);陈旭(辽宁石油化工大学 石油天然气工程学院);王丹(辽宁石油化工大学 石油天然气工程学院);刁照金(辽宁石油化工大学 石油天然气工程学院);张文建(辽宁石油化工大学 石油天然气工程学院);葛岚(辽宁石油化工大学 石油天然气工程学院)

Author:Wu Ming(College of Petroleum Eng.,Liaoning Shihua Univ.);Xie Fei(College of Petroleum Eng.,Liaoning Shihua Univ.);Chen Xu(College of Petroleum Eng.,Liaoning Shihua Univ.);Wang Dan(College of Petroleum Eng.,Liaoning Shihua Univ.);Diao Zhaojin(College of Petroleum Eng.,Liaoning Shihua Univ.);Zhang Wenjian(College of Petroleum Eng.,Liaoning Shihua Univ.);Ge Lan(College of Petroleum Eng.,Liaoning Shihua Univ.)

收稿日期:2012-12-08          年卷(期)页码:2013,45(5):185-191

期刊名称:工程科学与技术

Journal Name:Advanced Engineering Sciences

关键字:X80管线钢;焊缝;库尔勒土壤;腐蚀行为

Key words:X80 pipeline steel;weld joint;Ku’erle soil;corrosion behavior

基金项目:国家自然科学基金资助项目(50771053)

中文摘要

采用动电位极化、交流阻抗技术、失重法研究了X80管线钢及焊缝在库尔勒土壤模拟溶液中腐蚀行为,并结合X射线衍射仪(XRD)和金相显微镜(OM)对腐蚀产物及形貌进行表征。结果表明:随着浸泡时间的增加,金属腐蚀电位逐渐上升,电极表面的腐蚀产物层越来越厚,母材的腐蚀速率呈逐渐降低的趋势,而焊缝的腐蚀速率呈现减小后增大的趋势。金属电极表面内层的腐蚀产物膜Fe3O4对基体起到了一定的保护作用,减缓了X80钢及焊缝的腐蚀速率。当浸泡后期(30 d)时,焊缝的产物膜因大量脱落而出现裂纹,有利于溶液中Cl-等腐蚀性离子的侵入,加速局部腐蚀的进行。相同浸泡时间下,焊缝的腐蚀程度高于母材,这是由于焊接过程使焊缝组织结构产生了不均匀性,导致焊缝晶界处的晶格畸变能和活性偏高,耐腐蚀性能差。

英文摘要

The corrosion behavior of X80 pipeline steel in simulated Ku’erle soil solution was investigated by potentiodynamic polarization,electrochemical impedance spectroscopy (EIS) and mass loss measurement. The corrosion products and morphologies were observed by X-ray diffraction (XRD) and optical microscope (OM). The results showed that the longer the metal is in the solution,the higher the corrosion potential,and the thicker the corrosion products. However,the corrosion rate of weld joint decreases first and then increases. The corrosion rate of X80 steel and its weld joint slows down because of the protection from the corrosion product film of Fe3O4of inner layer. After 30 days in the solution,cracks show on the metal due to the shelling down of the corrosion product film,which is good for the invasion of Cl-. It accelerates the corrosion of certain part. The corrosion of weld joint part is more than other part of the steel in the exactly same solution environment. This is due to the fact that there are different structures on the same pipeline steel,leading to higher energy of lattice distortion and activity and lower corrosion resistance.

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