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论文摘要

城市污泥添加软锰矿制备活性炭的研究

Study on Preparation of Activated Carbon from Pyrolusite-Added Sewage Sludge

作者:谭显东(成都信息工程学院资源环境学院);陈红燕(成都信息工程学院);羊依金(成都信息工程学院资源环境学院);徐成华(成都信息工程学院资源环境学院);刘建英(1.成都信息工程学院资源环境学院; 2.四川大学建筑与环境学院);钱志勇(四川大学华西医院生物治疗国家重点实验室)

Author:Tan Xian-Dong(College of Resources and Environment, Chengdu University of Information Technology);();Yang Yi-Jin(College of Resources and Environment, Chengdu University of Information Technology);();刘建英();()

收稿日期:2010-01-20          年卷(期)页码:2011,43(2):156-160

期刊名称:工程科学与技术

Journal Name:Advanced Engineering Sciences

关键字:软锰矿,城市污泥,活性炭

Key words:pyrolusite, sewage sludge , activated carbon

基金项目:教育部新世纪人才基金项目(NCET-08-0371)

中文摘要

摘要 以城市污泥为原料,添加适量的软锰矿,采用氯化锌活化法制备活性炭。采用BET、SEM、FT-IR、O2-TPO、XRD、TGA等方法对其结构和性能进行了表征,并分析了软锰矿对活性炭制备过程的影响。研究结果表明,在实验条件下,城市污泥添加软锰矿制备的活性炭比表面积为354.198m2/g,总孔体积为0.8096cm3/g,微孔体积为0.159cm3/g,平均孔半径为4.6nm,碘吸附值为558.05mg/g。上述性能参数相较于纯污泥制备的活性碳都有较大程度的提高。在使用添加了软锰矿的城市污泥制备活性炭的过程中软锰矿催化了污泥中有机质的分解,同时也为新生炭提供了更多的骨架,促进了积炭反应,有助于形成孔隙发达的微晶结构。

英文摘要

Abstract: Activated carbon was prepared from pyrolusite-added sewage sludge by ZnCl2 activation method. Its structure and performance were characterized by BET, SEM, FT-IR, XRD, O2-TPO and TGA, and the impact of pyrolusite to preparing process of activated carbon was analyzed. The result showed that the specific surface area, total pore volume, micro-pore volume, average pore radius and iodine adsorption of activated carbon from pyrolusite-added sewage sludge can reach 354.198m2/g, 0.8096cm3/g, 0.159cm3/g, 4.6nm and 558.05mg/g respectively under the experiment condition, and the above performance parameters were increased in a great extent compared with activated carbon from sewage sludge. Pyrolusite catalyzed the decomposition of organics in the sewage sludge, supply the new generated carbon more framework, facilitated the carbon deposit and contributed to the formation of microcrystalline structure simultaneously in the preparing process of activated carbon from pyrolusite-added sewage sludge.

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