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论文摘要

碳酸锶基绿色荧光粉的制备及其发光性能

Preparation and Photoluminescence Properties of the SrCO3-based Green Phosphor

作者:康明(西南科技大学 四川省非金属复合与功能材料重点实验室-省部共建国家重点实验室培育基地);燕文清(西南科技大学 四川省非金属复合与功能材料重点实验室-省部共建国家重点实验室培育基地);刘军(西南科技大学 四川省非金属复合与功能材料重点实验室-省部共建国家重点实验室培育基地;海洋王照明科技股份有限公司);刘君玉(西南科技大学 四川省非金属复合与功能材料重点实验室-省部共建国家重点实验室培育基地);孙蓉(西南科技大学 四川省非金属复合与功能材料重点实验室-省部共建国家重点实验室培育基地);宋丽贤(西南科技大学 四川省非金属复合与功能材料重点实验室-省部共建国家重点实验室培育基地);宋开平(西南科技大学 四川省非金属复合与功能材料重点实验室-省部共建国家重点实验室培育基地)

Author:Kang Ming(State Key Lab. Cultivation Base for Nonmetal Composites and Functional Materials,Southwest Univ. of Sci. and Technol.);Yan Wenqing(State Key Lab. Cultivation Base for Nonmetal Composites and Functional Materials,Southwest Univ. of Sci. and Technol.);Liu Jun(State Key Lab. Cultivation Base for Nonmetal Composites and Functional Materials,Southwest Univ. of Sci. and Technol.;Oean’s King Lighting Sci. and Technol. Co. LTD.);Liu Junyu(State Key Lab. Cultivation Base for Nonmetal Composites and Functional Materials,Southwest Univ. of Sci. and Technol.);Saun Rong(State Key Lab. Cultivation Base for Nonmetal Composites and Functional Materials,Southwest Univ. of Sci. and Technol.);Song Lixian(State Key Lab. Cultivation Base for Nonmetal Composites and Functional Materials,Southwest Univ. of Sci. and Technol.);Song Kaiping(State Key Lab. Cultivation Base for Nonmetal Composites and Functional Materials,Southwest Univ. of Sci. and Technol.)

收稿日期:2010-12-27          年卷(期)页码:2011,43(5):209-212

期刊名称:工程科学与技术

Journal Name:Advanced Engineering Sciences

关键字:微波辅助;共沉淀法;碳酸锶;绿色荧光粉

Key words:microwave assisted;co-precipitation;SrCO3;green phosphor

基金项目:国家自然科学基金资助项目(10976023);西南科技大学研究生创新基金资助项目(09ycjj15);四川省生物质工程技术研究中心资助项目(09zxbk09)

中文摘要

采用微波辅助共沉淀法制备Sr(1-x)CO3:xTb^3+绿色荧光粉,并利用SEM、XRD、PL-PLE等仪器分别对样品的形貌、物相和发光性能进行表征。结果表明,样品由片状和类球形组成,掺杂Tb^3+作为发光中心进入到碳酸锶晶格中。该荧光粉的激发主峰位于231 nm处的4f^7→5d^1宽带吸收;发射光谱的最强发射峰位于543 nm处,对应于Tb^3+的^5D4→^7F5跃迁,属于绿色发光。研究Tb^3+离子掺量对样品发光性能的影响,随着Tb^3+离子掺杂浓度的增大,发光强度先增加后减小,最佳掺杂量x为3.5%。初步探讨Tb^3+离子的浓度猝灭机理为交换相互作用。

英文摘要

The Tb^3+-doped strontium carbonate phosphor was synthesized via co-precipitation route by microwave assisted.The phosphor powders were characterized by scanning electron microscopy(SEM),X-ray diffraction(XRD) and photoluminescence and photoluminescence excitation(PL-PLE) spectrum. The results showed that Tb^3+acting as a luminescent center probed into the single orthorhombic phase of SrCO3 with flake-like and sphericity-like.The PLE spectrum showed a broadband absorption center in 231 nm,which belonged to 4f7→5d1transition.The sample was the green phosphor since the maximum emission peak located in the vicinity of 543 nm,corresponding to the transition of ^5D4→^7F5.The luminescent intensities increased with increasing Tb^3+concentration, and then decreased because of concentration quenching.The optimal concentration of Tb^3+ was 3.5 mol%.The concentration self-quenching mechanism is exchange interaction.

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